Voor de duidelijkheid:
Heat vs. Temperature
Heat and temperature are not the same thing.
Heat energy is the total kinetic energy of the atoms of a substance.
Temperature is the average kinetic energy of the atoms of a substance.
Each atom has a certain amount of kinetic energy. This energy fluctuates due to the many collisions with other atoms. However, when two atoms collide transferring kinetic energy from one to the other, no kinetic energy is lost. If the amount of kinetic energy for each atom is added up then you would have a value representing the heat energy of that collection of atoms. It follows that the more atoms which are counted, the greater the heat energy will be.
Temperature is a measure of the average kinetic energy of those atoms. The result of this difference between heat and temperature causes the number of atoms measured to play a major role in understanding how much heat energy an object has at a particular temperature.
For example, if two glasses of water are left out on the table, one completely full and the other exactly half full, they will eventually both come to room temperature, about 21°C. They may have the same temperature, but the full glass has twice the heat energy of the half full glass. Because the full glass has twice as many molecules each carrying some heat energy (or kinetic energy) the full glass has more heat at the same temperature.
The higher the temperature the faster the atoms move.
Large objects can have a kinetic energy and temperature which are distinctly separate things. For example, a baseball sitting still has no kinetic energy, but its atoms are moving, so they have kinetic energy. Because the temperature of a substance is due to the average kinetic energy of its atoms, the ball does have a temperature. Depending on how many atoms it takes to make up the ball, it has a certain amount of heat energy (the total energy of the atoms comprising the ball).
Because temperature is a function of the average kinetic energy of the atoms, the lowest possible temperature would be when the atoms stop moving, therefore having no kinetic energy. Because there is a lowest possible temperature, it would make sense to use a temperature scale that starts at zero. This temperature scale is called the Kelvin temperature scale and zero Kelvin is a special temperature called absolute zero (when all atomic motion is stopped).
An atom, however, can't separate kinetic energy from heat energy. For atoms they are one and the same thing. A bunch of atoms sitting still have no kinetic energy, no heat energy, and would have zero temperature (on the Kelvin temperature scale).
In summary:
For an atom Kinetic Energy = Heat Energy
For a substance Heat Energy = Total of all the Kinetic Energies of its atoms
For a substance Temperature = Average Kinetic energy of its atoms
chemsite.lsrhs.net
Normaal worden alleen rotatie- en de trillings-energie verantwoordelijk gehouden voor temperatuur.
Voor rotatie:
E = L (L+1)
^2 / 2I met L = 0,1,2,3,...
Voor trilling:
E = ( v + 1/2 ) hf met v = 0,1,2,3,...
Die kunnen dus beide nul zijn. 0 Kelvin is dus mogelijk.
Ben je het nou niet eens met de aanname dat alleen de rotatie- en trillings-energie verantwoordelijk zijn voor de temperatuur maar ook het hoofdquantumgetal. Dan kan de temperatuur niet 0K worden omdat de n uit de functie van het hoofdquantumgetal nooit 0 is. Maar die discussie leid enkel tot filosofies getouwtrek.